Obviously if you are really attracted to someone or in love with someone it will affect your arousal with them. But, does it make it easier for you to orgasm?
Hmm... not an easy question for me. It depends on so many things not involving the guy. Hormones, time of the year, things that are on my mind, stress, distractions...
Also really depends on my kind of orgasm. There's the quicky-orgasm, to just get off. The way it's achieved doesn't really change, emotions don't really play a part in it. I don't even have to be aroused much to get it. I just want the orgasm to get the edge off and be able to function again properly, without being distracted all the time. So easy, quick, but not really fulfilling.
To get the big ones, my mind has to be in it completely. Any thoughts, feelings, emotions, things happening play a big part in that. When there's a guy in my life that is "playing my mind", both on emotional and a conscious level, the orgasm can be amazing.
So I guess no, it doesn't really make it "easier". It makes it different.
There's orgasms and Orgasms. I definitely prefer the second kind.